Journal of Chemical Sciences

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Journal of Chemical Sciences [Formerly: Proceedings of the Indian Academy of Sciences (Chemical Sciences)] Volume 128, 2016 CONTENTS Design and synthesis of nanoporous perylene bis-imide linked metalloporphyrin
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Journal of Chemical Sciences [Formerly: Proceedings of the Indian Academy of Sciences (Chemical Sciences)] Volume 128, 2016 CONTENTS Design and synthesis of nanoporous perylene bis-imide linked metalloporphyrin frameworks and their catalytic activity Manoj Kumar Singh and Debkumar Bandyopadhyay 1 8 Design and synthesis of ruthenium(ii) OCO pincer type NHC complexes and their catalytic role towards the synthesis of amides Muthukumaran Nirmala and Periasamy Viswanathamurthi 9 21 Synthesis, spectral properties and DNA binding and nuclease activity of lanthanide (III) complexes of 2-benzoylpyridine benzhydrazone: X-ray crystal structure, Hirshfeld studies and nitrate-π interactions of cerium(iii) complex Karreddula Raja, Akkili Suseelamma and Katreddi Hussain Reddy Iron(III) Chloride mediated reduction of Bis(1-isoquinolylcarbonyl)amide to an Amide Rojalin Sahu, Papuli Chaliha and Vadivelu Manivannan Synthesis, characterization and studies on antioxidant and molecular docking of metal complexes of 1-(benzo[d]thiazol-2-yl)thiourea Harinath Yapati, Subba Rao Devineni, Suresh Chirumamilla and Seshaiah Kalluru Formation of BH 3 Adducts with Pyridine-2-Methylaminophosphine ligands: An experimental and computational study Harinath Adimulam, Dwijendra P Kukri, Bhabani S Mallik and Tarun K Panda ,3,5-Trimethylpyrazolium chloride based ionogel as an efficient and reusable heterogeneous catalyst for the synthesis of benzimidazoles Pankaj Sharma and Monika Gupta Oxidative dehydrogenation of propane with K-MoO 3 /MgAl 2 O 4 catalysts Serkan Naci Koc, Kubra Dayioglu and Hasan Ozdemir Cycloisomerization of acetylenic oximes and hydrazones under gold catalysis: Synthesis and cytotoxic evaluation of isoxazoles and pyrazoles J C Jeyaveeran, Chandrasekar Praveen, Y Arun, A A M Prince and P T Perumal Synthesis and antibacterial activity of new chiral N-sulfamoyloxazolidin-2-ones Fouzia Bouchareb, Malika Berredjem, Samira Ait Kaki, Amel Bouaricha, Abdeslem Bouzina, Billel Belhani and Nour-Eddine Aouf Cu-MCM-41 nanoparticles: An efficient catalyst for the synthesis of 5-substituted 1H-tetrazoles via [3+2] cycloaddition reaction of nitriles and sodium azide Mohammad Abdollahi-Alibeik and Ali Moaddeli Thiophene-bithiazole based metal-free dye as DSSC sensitizer: Effect of co-adsorbents on photovoltaic efficiency Jayanthy S Panicker, Bijitha Balan, Suraj Soman, Tanwistha Ghosh and Vijayakumar C Nair i ii Experimental and theoretical investigation of benzyl-n-pyrrolylketene, one-step procedure for preparing of new β-lactams by [2+2] cycloaddition reaction Masoumeh Behzadi, Kazem Saidi, Mohammad Reza Islami and Hojatollah Khabazzadeh Effects of temperature and CO 2 pressure on the emission of N,N -dialkylated perylene diimides in poly(alkyl methacrylate) films. Are guest-host alkyl group interactions important? Kizhmuri P Divya, Michael J Bertocchi and Richard G Weiss Highly selective detection of Zn 2+ and Cd 2+ with a simple amino-terpyridine compound in solution and solid state Duobin Chao Impact of electric field on Hofmeister effects in aggregation of negatively charged colloidal minerals Ying Tang, Hang Li, Hualing Zhu, Rui Tian and Xiaodan Gao Anodization of Aluminium using a fast two-step process Murugaiya Sridar Ilango, Amruta Mutalikdesai and Sheela K Ramasesha Electron irradiation of carbon dioxide-carbon disulphide ice analog and its implication on the identification of carbon disulphide on Moon B Sivaraman Photocytotoxic ternary copper(ii) complexes of histamine Schiff base and pyridyl ligands Samya Banerjee, Akanksha Dixit, K Sesha Maheswaramma, Basudev Maity, Sanjoy Mukherjee, Arun Kumar, Anjali A Karande and Akhil R Chakravarty Silver(I) based dinuclear metallacycles with free thiophenyl/thiomethyl units Sarita Yadav, Deepak Gupta and Malaichamy Sathiyendiran Synthesis and crystal structure of [chlorobis(triphenylphospino)(p-chlorobenzaldehyde thiosemicarbazone)] copper(i) complex Ashiq Khan, Poonam Sharma, Rajnikant, Vivek K Gupta, Naresh Padha and Rekha Sharma Schiff base functionalized Organopropylsilatranes: Synthesis and structural characterization Gurjaspreet Singh, Promila, Amandeep Saroa, Jandeep Singh, Raj Pal Sharm and V Ferretti Chloro(triphenylphosphole)gold(I) - A selective Chemosensor for Cysteine Maruthai Kumaravel and Maravanji S Balakrishna Conformation driven complexation of two analogous benzimidazole based tripodal ligands with Ag(I) resulting in a trigonal prism and a coordination polymer Suman Bhattacharya and Binoy K Saha One-pot four component synthesis of novel 3-furyl coumarin derivatives Venkata Prasad Jalli, Suvratha Krishnamurthy, Tetsuji Moriguchi and Akihiko Tsuge Ammoxidation of 2-methyl pyrazine to 2-cyano pyrazine on MoO 3 /FePO 4 catalysts Nagaraju Pasupulety, Hafedh Driss, Yahia Abobakor Alhamed, Abdulrahim Ahmed Alzahrani, Muhammad A Daous, Lachezar Petrov, N Lingaiah and P S Sai Prasad Experimental and theoretical rearrangement of N-acyl-2,2- dimethylaziridines in acidic medium Madiha Kamoun Mhiri, Firas Aboumessaad, Mohamed Lotfi Efrit, Youssef Arfaoui and Néji Besbes Palladium(II)-catalyzed oxidation of L-tryptophan by hexacyanoferrate(iii) in perchloric acid medium: a kinetic and mechanistic approach Ahmed Fawzy Acriflavine immobilized onto polyethyleneimine-wrapped carbon nanotubes/gold nanoparticles as an eletrochemical sensing platform Azadeh Azadbakht and Amirreza Abbasi Unexpected regiospecific formation and DNA binding of new 3-(acridin-9-yl)methyl-2-iminothiazolidin-4-ones Ján Imrich, Danica Sabolová, Mária Vilková and Júlia Kudláčová iii Theoretical insights into the cycloaddition reaction mechanism between ketenimine and methyleneimine: An alternative approach to the formation of pyrazole and imidazole Nana Wang, Xiaojun Tan, Weihua Wang, Fangfang Wang and Ping Li Ab initio adiabatic and quasidiabatic potential energy surfaces of H + + CN system Bhargava Anusuri and Sanjay Kumar Functionalized organic frameworks explored as second order NLO agents Anil K Singh, Brijesh Rathi, Volodymyr V Medviediev, Oleg V Shishkin, Vijay Bahadur, Taruna Singh, Brajendra K Singh, N Vijayan, V Balachandran and Nikolay Yu Gorobets Does oligomerization in fused thiophene affect reactivity and aromaticity? Siddhartha Kr Purkayastha and Pradip Kr Bhattacharyya Facile synthesis of Graphene Oxide/Double-stranded DNA composite liquid crystals and Hydrogels Rajendra Kurapati, U Venkateswara Reddy, Ashok M Raichur and N Suryaprakash Electroless deposition of Gold-Platinum Nanoparticles on Glassy Carbon Electrode for Non-Enzymatic Hydrogen Peroxide sensing N S K Gowthaman and S Abraham John On the electrocatalytic activity of nitrogen-doped reduced graphene Oxide: Does the nature of nitrogen really control the activity towards oxygen reduction? Sourav Bag and C Retna Raj Synthesis and characterization of gold nanoparticles incorporated bentonite clay for electrocatalytic sensing of arsenic(iii) Pankaj Kumar Rastogi, Dharmendra Kumar Yadav, Shruti Pandey, Vellaichamy Ganesan, Piyush Kumar Sonkar and Rupali Gupta Facile growth of bimetallic nanorods on electrochemically reduced graphene oxide for an enhanced electrooxidation of hydrazine S E Jeena and T Selvaraju A density functional investigation on the electronic and magnetic properties of LnSi (Ln=La-Lu) Diatom Run-Ning Zhao, Rui Chen, Yan-Hong Yuan, Fan Gu and Ju-Guang Han Synthesis and solid state structures of Chalcogenide compounds of Imidazolin-2-ylidene-1,1-Diphenylphosphinamine Kishor Naktode, Suman Das, Abhinanda Kundu, Hari Pada Nayek and Tarun K Panda A new Organopalladium compound containing four Iron (III) Porphyrins for the selective oxidation of alkanes/ alkenes by t-buooh Manoj Kumar Singh and Debkumar Bandyopadhyay Synthesis, DNA binding and cytotoxic evaluation of aminoquinoline scaffolds Gopal Senthil Kumar, Mohamed Ashraf Ali, Tan Soo Choon and Karnam Jayarampillai Rajendra Prasad Effect of methionine and glucosamine conjugation on the anticancer activity of aromatic dinitrobenzamide mustards Subhendu Karmakar, Sudipta Bhattacharyya and Arindam Mukherjee Synthesis of low polydisperse isotactic poly(n-isopropylacrylamide)s in environment-friendly and less toxic methanol-water mixtures by RAFT polymerization Chandra Sekhar Biswas, Kheyanath Mitra, Shikha Singh and Biswajit Ray Synthesis, crystal structure and properties of magnesium and calcium salts of p-anisic acid Kiran T Dhavskar, Pooja H Bhargao and Bikshandarkoil R Srinivasan iv An efficient and convenient synthesis of N-substituted amides under heterogeneous condition using Al(HSO 4 ) 3 via Ritter reaction Elnaz Karimian, Batool Akhlaghinia and Sara S E Ghodsinia An efficient synthesis of 8-substituted Odoratine derivatives by the Suzuki coupling reaction P Ravi Kumar, C Balakrishna, B Murali, Ramakrishna Gudipati, Prasanta K Hota, Avinash B Chaudhary, A Jaya Shree, Satyanarayana Yennam and Manoranjan Behera Transition metal-free, base-promoted hydroalkoxylation: Synthesis of substituted imidazo[2,1-c][1,4]oxazines Muthupandi Nagaraj and Shanmugam Muthusubramanian Extended structures of two coordination polymers based on 1,10-phenanthroline derivatives: Preparation, structural characterization and properties Yan-Ju Huang, Ya-Ru Pan, Gang Du and Yi-Xin Cao Synthesis and characterization of Polyindole and its catalytic performance study as a heterogeneous catalyst Prakash Chhattise, Kalpana Handore, Amit Horne, Kakasaheb Mohite, Atul Chaskar, Sabrina Dallavalle and Vasant Chabukswar Thermodynamic, kinetic and mechanistic investigations of Piperazine oxidation by Diperiodatocuprate(III) complex in aqueous alkaline medium Vijay P Pattar, Prashant A Magdum, Deepa G Patil and Sharanappa T Nandibewoor On the issues of resolving a low melting combination as a definite eutectic or an elusive cocrystal: A critical evaluation Suryanarayan Cherukuvada Crystal structures of meso-tetrakis(2,6 /3,5 -difluorophenyl)porphyrins and their metal complexes: Influence of position of the fluoro groups on their structural properties Bhyrappa Puttaiah and Karuppaiah Karunanithi Pyrone-based Cu(II) complexes, their characterization, DFT based conformational drift from square planar to square pyramidal geometry and biological activities Pradeep Kumar Vishwakarma, Jan Mohammad Mir and Ram Charitra Maurya Mn(II) complexes with bipyridine, phenanthroline and benzoic acid: Biological and catalase-like activity Ibrahim Kani, Özlem Atlier and Kiymet Güven An interesting spectroscopic method for chromofluorogenic detection of cyanide ion in aqueous solution: Disruption of intramolecular charge transfer (ICT) Abdolhamid Alizadeh, Sohrab Ghouzivand, Mohammad M Khodaei and Mehdi Ardalani Synthesis, characterization and photophysical studies of β-triazolomethyl-bridged porphyrin-benzo-α-pyrone dyads Dileep Kumar Singh and Mahendra Nath Synthesis of Diphenyl Pyridazinone-based flexible system for conformational studies through weak noncovalent interactions: Application in DNA binding Ranjeet Kumar, Praveen Singh, Archana Gaurav, Pratima Yadav, Ranjana S Khanna and Ashish Kumar Tewari One pot synthesis of 1-substituted tetrahydro-β-carbolines by Bischler Napieralski cyclization Thokchom Prasanta Singh and Okram Mukherjee Singh Kinetics of the thermal decomposition of tetramethylsilane behind the reflected shock waves between 1058 and 1194 K A Parandaman and B Rajakumar v Reactivity of chitosan derivatives and their interaction with guanine: A computational study Bhabesh Chandra Deka and Pradip Kr Bhattacharyya Salting-out of methane in the aqueous solutions of urea and sarcosine M K Dixit, Anupam Chatterjee and B L Tembe Investigation on reactivity of non-classical carbenes with sterically hindered Lewis acid, B(C 6 F 5 ) 3 under inert and open conditions Arunabha Thakur, Pavan K Vardhanapu, Gonela Vijaykumar and Sushil Ranjan Bhatta Interactions between metal cations with H 2 in the M + -H 2 complexes: Performance of DFT and DFT-D methods Srimanta Pakhira, Tanay Debnath, Kaushik Sen and Abhijit K Das DFT analysis of the nucleophilicity of substituted pyridines and prediction of new molecules having nucleophilic character stronger than 4-pyrrolidino pyridine Kaustavmoni Deka and Prodeep Phukan Co-catalyst free Titanate Nanorods for improved Hydrogen production under solar light irradiation N Lakshmana Reddy, D Praveen Kumar and M V Shankar Sulfamic acid as energy efficient catalyst for synthesis of flurophores, 1-H-spiro [isoindoline-1,2 -quinazoline]- 3,4 (3 H)-diones Mansing M Mane and Dattaprasad M Pore Preparation, characterization and photocatalytic studies of Cu 2+,Sn 2+ and N 3 substituted K 5 Sb 5 P 2 O 20 Ch Sudhakar Reddy, Sreenu K, J R Reddy, A Hari Padmasri, Ravi Gundeboina and M Vithal nanoparticles-driven expeditious synthesis of biologically active benzo[4,5]imidazo[1,2-a]chromeno[4, 3-d]pyrimidin-6-one scaffolds: A green approach Vilas N Mahire, Vijay E Patel, Ashok B Chaudhari, Vikas V Gite and Pramod P Mahulikar Uncatalyzed thermal gas phase aziridination of alkenes by organic azides. Part I: Mechanisms with discrete nitrene species S Premila Devi, Tejeshwori Salam and R H Duncan Lyngdoh Coupling of temperature with pressure induced initial decomposition mechanisms of two molecular crystals: An ab initio molecular dynamics study Qiong Wu, Dong Xiang, Guolin Xiong, Weihua Zhu and Heming Xiao Quantum chemical study of the mechanisms of oxidation of ethylene by Molybdyl and Tungstyl Chloride Richard Tia, Evans Adei, Joseph Baidoo and Juliana Edor Dynamic ligand-based pharmacophore modeling and virtual screening to identify mycobacterial cyclopropane synthase inhibitors Chinmayee Choudhury, U Deva Priyakumar and G Narahari Sastry Kinetics and mechanism of uncatalyzed and ruthenium(iii)-catalyzed oxidation of formamidine derivative by hexacyanoferrate(iii) in aqueous alkaline medium Ahmed Fawzy Thermolysis of some N-arylbenzamidoximes: Mechanistic studies for formation of anilide, oxazole and imidazole derivatives Abdel-Aal Gaber and Layla Taib Are N-methyl groups of Tetramethylurea (TMU) Hydrophobic? A composition and temperature-dependent fluorescence spectroscopic investigation of TMU/water binary mixtures Sandipa Indra and Ranjit Biswas vi Development of highly selective electrochemical impedance sensor for detection of sub-micromolar concentrations of 5-Chloro-2,4-dinitrotoluene K Yugender Goud, Satyanarayana M, K Koteshwara Reddy and K Vengatajalabathy Gobi Different carboxylic acid homodimers in self-assemblies of adducts of 3-carboxyphenoxyacetic acid with nitrogen containing compounds Krapa Shankar and Jubaraj B Baruah Synthesis of new hybrid sorbent by grafting 2,6-diacetyl pyridine onto microporous β-zeolite and its application in solid phase extraction of heavy metals from environmental samples Harinath Yapati, Sreenu Bhogineni, Suresh Chirumamilla and K Seshaiah Flexible synthesis of isomeric pyranoindolones and evaluation of cytotoxicity towards HeLa cells J C Jeyaveeran, Chandrasekar Praveen, Y Arun, A A M Prince and P T Perumal Synthesis and structure of copper(ii) complexes: Potential cyanide sensor and oxidase model Palash Mondal, Sankar Prasad Parua, Poulami Pattanayak, Uttam Das and Surajit Chattopadhyay Synthesis, crystal structure and characterization of new biologically active Cu(II) complexes with ligand derived from N-substituted sulfonamide Adriana Corina Hangan, Alexandru Turza, Roxana Liana Stan, Bogdan Sevastre, Emöke Páll, Sînziana Cetean and Luminiţa Simona Oprean Hydrothermal synthesis and electrochemical properties of a coordination polymer based on dinuclear (Pyrazinyl tetrazolate) Copper(II) cations and β-octamolybdate Anions Shaobin Li, Li Zhang, Huiyuan Ma and Haijun Pang Effect of citric acid on formation of oxides of Cu and Zn in modified sol-gel process: A comparative study Kamaraj Mahendraprabhu and Perumal Elumalai Synthesis of silver nanoparticles-decorated FePO 4 nanosphere at a gas-liquid interface for the electrochemical detection of Hydrogen peroxide Dejiang Rao, Jian Zhang and Jianbin Zheng Copper (0) nanoparticles onto silica: A stable and facile catalyst for one-pot synthesis of 2,2 -arylmethylene bis (3- hydroxy-5,5-dimethyl-2-cyclohexene-1-one) via cascade Knoevenagel/Michael reaction Manjulla Gupta and Monika Gupta Synthesis and catalytic activity of metallo-organic complexes bearing 5-amino 2-ethylpyridine -2-carboximidate Luo Mei, Xu Jia and Zhang Jing Cheng Catalytic activity of CuO-Gd 0.1 Ti 0.1 Zr 0.1 Ce 0.7 O 2 in CO oxidation Igor V Zagaynov and Elena Yu Liberman Amidinate Ligands in Zinc coordination sphere: Synthesis and structural diversity Srinivas Anga, Indrani Banerjee and Tarun K Panda Zinc catalyzed Guanylation reaction of Amines with Carbodiimides/ Isocyanate leading to Guanidines/Urea derivatives formation Jayeeta Bhattacharjee, Mitali Sachdeva, Indrani Banerjee and Tarun K Panda Salicylaldimine Copper(II) complex catalyst: Pioneer for ring opening Polymerization of Lactide Anita Routaray, Nibedita Nath, Tungabidya Maharana, Pratap Kumar Sahoo, Jaya Prakash Das and Alekha Kumar Sutar Synthesis and structures of two new Cu(I) frameworks bearing1,3-bis(4-pyridyl)propane and inorganic linkers Zhaobo Hu, Bo Li, Wenqiang Ju, Yuning Liang and Zilu Chen vii Synthesis, crystal structure and Thermogravimetry of ortho-phthalic acid bridged coordination polymer of Copper(II) Babita Sarma, Saurav Bharali and Diganta Kumar Das Synthesis, crystal structure and magnetic properties of 1-(2,5-dimethylphenyl) piperazine-1,4-dium tetrachloridocuprate(ii) L Khedhiri, Jin-Xiao Mi, M Rzaigui and C Ben Nasr Crystal structure, characterization and magnetic properties of a 1D copper(ii) polymer incorporating a Schiff base with carboxylate side arm Shyamapada Shit, Madhusudan Nandy, Corrado Rizzoli, Cédric Desplanches and Samiran Mitra Triethylammonium salt of dimethyl diphenyldithiophosphates: Single crystal X-ray and DFT analysis Sandeep Kumar, Ruchi Khajuria, Mandeep Kour, Rakesh Kumar, Love Karan Rana, Geeta Hundal, Vivek K Gupta, Rajni Kant and Sushil K Pandey Synthesis, biological evaluation and molecular docking studies of some novel cyclopropane carbohydrazide derivatives as potential anticancer agents Ponnapalli Veerabhadra Swamy, Pullaiah China Kambhampati, Kothapalli Bonnoth Chandrasekhar, Gugulothu Thirupathi, Pombala Sujitha, Chityal Ganesh Kumar and Veeramachaneni Ganesh Kumar Effect of Isotacticity of Linear Poly(N-isopropylacrylamide) on its Gelation in Benzyl Alcohol Chandra Sekhar Biswas, Kheyanath Mitra, Shikha Singh, Dinesh K Patel, Biswajit Maiti, Pralay Maiti and Biswajit Ray Triflic Anhydride-Mediated Beckmann Rearrangement Reaction of β-oximyl Amides: Access to 5- Iminooxazolines Mangfei Yu, Qian Zhang, Jia Wang, Peng Huang, Pengfei Yan, Rui Zhang and Dewen Dong Direct synthesis of dimethyl carbonate from CO 2 and methanol over CeO 2 catalysts of different morphologies Unnikrishnan P and Srinivas Darbha Domino Knoevenagel/Michael synthesis of 2,2 -arylmethylenebis(3-hydroxy-5,5-dimethyl-2-cyclohexen-1-one) derivatives catalyzed by silica-diphenic acid and their single crystal X-ray analysis Rupali Vaid, Monika Gupta, Rajni Kant and Vivek K Gupta Rate coefficients for hydrogen abstraction reaction of pinonaldehyde (C 10 H 16 O 2 ) with Cl atoms between 200 and 400 K: A DFT study G Srinivasulu and B Rajakumar Effects of dimethyl sulfoxide on the hydrogen bonding structure and dynamics of aqueous N-methylacetamide solution Apramita Chand and Snehasis Chowdhuri Na + Cl ion pair association in water-dmso mixtures: Effect of ion pair model potentials Atanu Sarkar, Anupam Chatterjee, S C Tiwari and B L Tembe Characterization of Ag/Ag 2 SO 4 system as reference electrode for in-situ electrochemical studies of advanced aqueous supercapacitors Denys G Gromadskyi A simple approach to the construction of the core structure present in bielschowskysin and hippolachnin A Ritabrata Datta, Malasala Sumalatha and Subrata Ghosh Reactivity of [Cp*Mo(CO) 3 Me]
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